Functionalization of melamine sponge for the efficient recovery of Pt(IV) from acid leachates

Abstract

The recovery of platinum from industrial waste is of critical importance. Usually, the recovery method is to dissolve the solid waste with acid to form a solution where platinum mainly exists in the form of Pt(IV). Therefore, it is urgent to efficiently and selectively adsorb Pt(IV) ions from acid leachates. In this study, a highly efficient adsorbent was developed by grafting of carboxyl and amine groups onto melamine sponge with alginate-Ca and polyethylenimine-glutaraldehyde (ML/ACPG). Combination of SEM, FTIR and XPS showed that the ML/ACPG sponge had a tree structure and the amino, carboxyl and hydroxyl groups were successfully introduced. Maximum adsorption capacity of ML/ACPG sponge reached up to 101.1 mg/L at pH of 1 (optimum initial pH value). The Pt(IV) ions were readily desorbed (within 60-80 min) using 0.1 M HCl + 0.025 M thiourea solution. Desorption efficiency remained higher than 83.3% while adsorption capacity decreased by less than 6.0% after 5 cycles operation. The ML/ACPG sponge was stable in 3 M of HNO₃, NaCl after shaking for 72 h at 300 rpm with mass loss less than 2.5%. The mechanism of Pt(IV) adsorption onto ML/ACPG sponge mainly involved coordination by electrostatic attraction and carboxyl groups by protonated amine groups. The above results confirmed that the ML/ACPG sponge has a good practical application potential for Pt(IV) recovery from acid leachates.

Keywords: Double-crosslinked modification; Melamine sponge; Pt(IV) recovery; Sorbent recycling.