Improving the efficiency of ternary organic solar cells by reducing energy loss

Mengni Wang; Yanan Shi; Ziqi Zhang; Yifan Shen; Min Lv; Yangjun Yan; Huiqion Zhou; Jianqi Zhang; Kun Lv; Yajie Zhang; Hailin Peng; Zhixiang Wei

doi:10.1039/d3nh00122a

Improving the efficiency of ternary organic solar cells by reducing energy loss

Nanoscale Horiz. 2023 Jul 24;8(8):1073-1081. doi: 10.1039/d3nh00122a.

Authors

Mengni Wang^{1

2

3}, Yanan Shi^{1

2}, Ziqi Zhang^{1

2}, Yifan Shen^{1

2}, Min Lv^{1

2}, Yangjun Yan⁴, Huiqion Zhou^{1

2}, Jianqi Zhang^{1

2}, Kun Lv^{1

2}, Yajie Zhang^{1

2}, Hailin Peng⁵, Zhixiang Wei^{1

2}

Affiliations

¹ Chinese Academy of Sciences (CAS) key laboratory of nanosystem and hierarchical fabrication, National Center for Nanoscience and Technology, Beijing 100190, China. zhangyj@nanoctr.cn.
² University of Chinese Academy of Sciences, Beijing 100049, China.
³ Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, People's Republic of China.
⁴ School of Science, Beijing Jiaotong University, Beijing 100044, China.
⁵ Center for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China. hlpeng@pku.edu.cn.

PMID: 37345335
DOI: 10.1039/d3nh00122a

Abstract

Effectively reducing the voltage loss in organic solar cells (OSCs) is critical to improving the power conversion efficiency (PCE) of OSCs. In this study, highly efficient ternary OSCs were constructed by adding a non-fullerene acceptor Qx2 with a high open-circuit voltage (V_OC) and low energy loss (E_loss) into PM6:m-BTP-PhC6 based binary devices. The third component Qx2 shows slightly complementary absorption with m-BTP-PhC6 and also optimizes the molecular packing, orientation, and morphology of the active layer. Moreover, the incorporation of Qx2 reduced the energetic disorder and improved the electroluminescence quantum efficiency, which suppresses the E_loss and further leads to a higher V_OC than the PM6:m-BTP-PhC6 binary blend. Consequently, synergetic enhancements of V_OC, short circuit current (J_SC), and fill factor (FF) are realized, resulting in the PCE of 18.60%. This work shows that the selection of the appropriate third component has positive implications for reducing E_loss and improving the PCE of OSCs.