Catalytic degradation of benzene over non-thermal plasma coupled Co-Ni binary metal oxide nanosheet catalysts

Abstract

Non-thermal plasma (NTP) has been demonstrated as one of the promising technologies that can degrade volatile organic compounds (VOCs) under ambient condition. However, one of the key challenges of VOCs degradation in NTP is its relatively low mineralization rate, which needs to be addressed by introducing catalysts. Therefore, the design and optimization of catalysts have become the focus of NTP coupling catalysis research. In this work, a series of two-dimensional nanosheet Co-Ni metal oxides were synthesized by microwave method and investigated for the catalytic oxidation of benzene in an NTP-catalysis coupling system. Among them, Co₂Ni₁O_x achieves 60% carbon dioxide (CO₂) selectivity (S_CO2) when the benzene removal efficiency (RE_benzene) reaches more than 99%, which is a significant enhancement compared with the CO₂ selectivity obtained without any catalysts (38%) under the same input power. More intriguingly, this S_CO2 is also significantly higher than that of single metal oxides, NiO or Co₃O₄, which is only around 40%. Such improved performance of this binary metal oxide catalyst is uniquely attributed to the synergistic effects of Co and Ni in Co₂Ni₁O_x catalyst. The introduction of Co₂Ni₁O_x was found to promote the generation of acrolein significantly, one of the key intermediates found in NTP alone system reported previously, suggest the benzene ring open reaction is promoted. Compared with monometallic oxides NiO and Co₃O₄, Co₂Ni₁O_x also shows higher active oxygen proportion, better oxygen mobility, and stronger low-temperature redox capability. The above factors result in the improved catalytic performance of Co₂Ni₁O_x in the NTP coupling removal of benzene.

Keywords: Benzene; Binary metal oxide; Catalysis; Cobalt metal oxide; Nickel oxide; Nonthermal plasma.