Sodium-ion hybrid capacitors (SIHCs) in principle can utilize the advantages of batteries and supercapacitors and satisfy the cost demand of large-scale energy storage systems, but the sluggish kinetics and low capacities of its anode and cathode are yet to be overcome. Here, a strategy is reported to realize high-performance dual-carbon SIHCs using 3D porous graphitic carbon cathode and anode materials derived from metal-azolate framework-6s (MAF-6s). First, MAF-6s, with or without urea loading, are pyrolyzed to synthesize MAF-derived carbons (MDCs). Then, cathode materials are synthesized via the controlled KOH-assisted pyrolysis of MDCs (K-MDCs). K-MDCs, 3D graphitic carbons, resulting in a record-high surface area (5214 m2 g-1 ) being ≈four-fold higher than pristine MAF-6, oxygen-doped sites for high capacity, rich mesopores affording fast ion transport, and high capacity retention over 5000 charge/discharge cycles. Moreover, 3D porous MDC anode materials are synthesized from N-containing MAF-6 and exhibited to allow cycle stability over 5000 cycles. Furthermore, dual-carbon MDC//K-MDC SIHCs with different loadings (3 to 6 mg cm-2 ) are demonstrated to achieve high energy densities exceeding those of sodium-ion batteries and supercapacitors. Additionally, it allows an ultrafast-chargeable high power density of 20000 W kg-1 and robust cycle stability overcoming those of a typical battery.
Keywords: dual-carbon sodium-ion hybrid capacitors; high energy densities, fast chargeable power densities, and robust cycle stabilities; metal-azolate frameworks; porous nitrogen-doped graphitic carbon anodes; ultrahigh surface area porous oxygen-doped graphitic carbon cathodes.
© 2023 The Authors. Advanced Science published by Wiley-VCH GmbH.