In this study, we report chemical species of Cs and I in condensed vaporized particles (CVPs) produced by melting experiments using nuclear fuel components containing CsI with concrete. Analyses of CVPs by SEM with EDX showed the formation of many round particles containing Cs and I of diameters less than ∼20 μm. X-ray absorption near-edge-structure and SEM-EDX analyses showed two kinds of particles: one containing large amounts of Cs and I, suggesting the presence of CsI, and the other containing small amounts of Cs and I with large Si content. When CVSs were placed in contact with deionized water, most of the CsI from both particles was dissolved. In contrast, some fractions of Cs remained from the latter particles and possessed different chemical species from CsI. In addition, the remaining Cs was concomitantly present with Si, resembling chemical components in the highly radioactive cesium-rich microparticles (CsMPs) released by nuclear plant accidents into the surrounding environments. These results strongly suggest that Cs was incorporated in CVSs along with Si by melting nuclear fuel components to form sparingly-soluble CVMPs.