Bioinspired Near-Full Transmittance MgF2 Window for Infrared Detection in Extremely Complex Environments

ACS Appl Mater Interfaces. 2023 Jun 28;15(25):30985-30997. doi: 10.1021/acsami.3c04170. Epub 2023 Jun 14.

Abstract

Due to the extreme complexity of the anti-reflective subwavelength structure (ASS) parameters and the drastic limitation of Gaussian beam manufacturing accuracy, it remains a great challenge to manufacture ASS with ultrahigh transmittance on the surface of infrared window materials (such as magnesium fluoride (MgF2)) directly by femtosecond laser. Here, a design, manufacturing, and characterization method that can produce an ultrahigh-performance infrared window by femtosecond laser Bessel beam is proposed. Inspired by the excellent anti-reflective and hydrophobic properties of the special structure of dragonfly wings, a similar structural pattern with grid-distributed truncated cones is designed and optimized for its corresponding parameters to achieve near-full transmittance. The desired submicron structures are successfully fabricated by a Bessel beam after effectively shaping the beam. As a practical application, the bioinspired ASS is manufactured on the surface of MgF2, achieving an ultrahigh transmittance of 99.896% in the broadband of 3-5 μm, ultrawide angle of incidence (over 70% at 75° incidence), and good hydrophobicity with a water contact angle of 99.805°. Results from infrared thermal imaging experiments show that the ultrahigh-transmittance MgF2 window has superior image acquisition and anti-interference performance (3.9-8.6% image contrast enhancement and more accurate image edge recognition) in an environment with multiple interfering factors, which may play a significant role in facilitating applications of infrared thermal imaging technologies in extremely complex environments.

Keywords: bioinspired microstructure; femtosecond laser; infrared thermo-imaging; magnesium fluoride; near-full transmittance.