Physical properties, chemical composition, and toxicity leaching of incineration fly ash by multistage water washing

Abstract

Incineration fly ash contains a large amount of chloride, which limits the scope of its resource utilization. Water washing effectively removes chlorides and soluble substances, increasing the ability to dispose of them. The properties of incineration fly ash after multi-level water washing have been studied, providing theoretical guidance for the safe disposal of water-washed ash at all levels. Taking a practical project as an example, this paper analyzed the impact of three-stage countercurrent water washing on the physicochemical properties and toxicity leaching of incineration fly ash with different washing grades by XRD, BET, XRF, SEM, and ICP-MS. The results showed that with the improvement of washing grade, the removal rate of chloride ions was more than 86.96%. However, due to the removal of soluble substances, dioxins enriched from 98 ng-TEQ/kg of raw ash to 359 ng-TEQ/kg of tertiary washed incineration fly ash. Cr, Cu, and Zn also increased from 40.35 mg/L, 356.55 mg/L, and 3290.58 mg/L of raw ash to 136.30 mg/L, 685.75 mg/L, and 5157.88 mg/L, respectively. Pozzolanic activity had increased from 40.56% of the raw ash to 74.12% of the tertiary-washed incineration fly ash. There was no risk of excessive heavy metal leaching, and the dioxin content was lower than the raw ash in the primary washed incineration fly ash. After multi-stage water washing, incineration fly ash accumulated heavy metals, so more attention must be paid to the issue of heavy metal content in the safe disposal process.

Keywords: Heavy metal leaching; Incineration fly ash; Micromorphology; Physicochemical properties.