The extensive use of perovskites as light absorbers calls for a deeper understanding of the interaction of these materials with light. Here, the evolution of the chemical and optoelectronic properties of formamidinium lead tri-bromide (FAPbBr3 ) films is tracked under the soft X-ray beam of a high-brilliance synchrotron source by photoemission spectroscopy and micro-photoluminescence. Two contrasting processes are at play during the irradiation. The degradation of the material manifests with the formation of Pb0 metallic clusters, loss of gaseous Br2 , decrease and shift of the photoluminescence emission. The recovery of the photoluminescence signal for prolonged beam exposure times is ascribed to self-healing of FAPbBr3 , thanks to the re-oxidation of Pb0 and migration of FA+ and Br- ions. This scenario is validated on FAPbBr3 films treated by Ar+ ion sputtering. The degradation/self-healing effect, which is previously reported for irradiation up to the ultraviolet regime, has the potential of extending the lifetime of X-ray detectors based on perovskites.
Keywords: perovskites; photoemission spectroscopy; photoluminescence imaging; self-healing; soft X-rays.
© 2023 The Authors. Small Methods published by Wiley-VCH GmbH.