Elemental doping is one of the most essential techniques for material modification. It is well known that fluorine is considered to be a highly efficient and inexpensive dopant in the field of materials. Fluorine is one of the most reactive elements with the highest electronegativity (χ = 3.98). Compared to cationic doping, anionic doping is another valuable method for improving the properties of materials. Many materials have physicochemical limitations that affect their practical application in the field of catalysis and rechargeable ion batteries. Many researchers have demonstrated that F-doping can significantly improve the performance of materials for practical applications. This paper reviews the applications of various F-doped materials in photocatalysis, electrocatalysis, lithium-ion batteries, and sodium-ion batteries, as well as briefly introducing their preparation methods and mechanisms to provide researchers with more ideas and options for material modification.
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