CO2 conversion is an anticipated route to resolve the energy crisis and environmental pollution, in which electrocatalysis is one of the technologies closest to industrialization. Alloy catalysts are promising candidates for electrocatalysis, and the high tenability in electronic structures and surface physical and chemical properties allows alloy catalysts high catalytic activity and selectivity for electrocatalytic CO2 reduction. Herein, the recent advances in alloy catalysts for electrocatalytic CO2 reduction have been systematically summarized, with insight into the structure of the active center, catalytic performance, and mechanism, to uncover the key to their high catalytic performance. The alloy catalysts are mainly classified as binary and multi-metallic alloys (medium entropy and high entropy alloy) based on components and mixed configuration entropy, on which the relationship among the active center, catalytic performance, and mechanism has been fully discussed to inspire the rational design of alloy catalysts. Finally, the current challenges and future perspectives are presented to propose the dilemma and development direction for alloy catalysts. This review provides an overview of about the recent progress and future development of alloy catalysts to present a guideline for future research work on relevant catalysts.
Keywords: CO2 reduction; alloy catalysts; d-band center; electrocatalysis; high-entropy alloys.
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