A and B sites dual substitution by Na+ and Cu2+ co-doping in CsPbBr3 quantum dots to achieve bright and stable blue light emitting diodes

Abstract

Light-emitting perovskite quantum dots (PeQDs) are extensively investigated owing to their evident merits. However, it is still a challenge to adjust their intrinsic emissions and enhance their thermal stability to achieve full-color highly emissive QD-based light-emitting diodes (QLEDs), especially blue QLEDs. Herein, we demonstrate an effective strategy to fundamentally stabilize the crystal structure of CsPbBr₃ QDs by codoping Na⁺ and Cu²⁺ ions, which are designed to substitute Cs⁺ (A sites) and Pb²⁺ (B sites), respectively. It is found out that the codoping metal ions have significantly improved the thermal stability and the optical properties of the QDs. 40% of the emission intensity can be remained after 8 thermal cycles (20-120 °C) for CsPbBr₃: Na⁺/Cu²⁺ QDs, whilst less than 10% is maintained for undoped CsPbBr₃ QDs. Accordingly, stable blue QLEDs are packed by CsPbBr₃: Na⁺/Cu²⁺ QDs. Strong electroluminescence with the maximum luminance of 7161 cd m^-2 and low turn-on voltage of 2.4 V are realized. The CIE coordinates are tuned from green (0.10, 0.74) to blue (0.17, 0.25) via Na⁺ and Cu²⁺ codoping. The maximum external quantum efficiency (EQE_max) is obtained as 4.52% for PeLEDs based on codoped QDs. The proposed metal ions A and B sites dual substitution strategy guarantees PeQDs as an extremely promising prospect in potential applications as high-resolution displays and high-quality lightings.

Keywords: CsPbBr(3) perovskite QDs; Doping; Light-emitting diodes; Optical performance; Thermal stability.