Dissipation, metabolism, accumulation, processing and risk assessment of fluxapyroxad in cucumber and cowpea vegetables from field to table

Abstract

Understanding the residue fate of fluxapyroxad is critical for food safety and human health. The present study profiled the dissipation, metabolism, accumulation, removal and risk assessment of fluxapyroxad in cucumbers and cowpeas from field to table. Greenhouse-field trials suggested that fluxapyroxad dissipated faster in cucumbers than in cowpeas, and M700F008 was the only detected metabolite at <LOQ-37.92 μg/kg. Fluxapyroxad accumulated in cucumbers (average residue accumulation value, 1: 2.21: 1.16) and cowpeas (1: 1.33: 1.05) after repeated spraying. Peeling, washing and parboiling could remove fluxapyroxad from cucumbers and cowpeas (PF range, 0.16-0.85); however, fluxapyroxad was partly concentrated by stir-frying (PF range, 0.36-1.41). Moreover, fluxapyroxad residues increased with increasing pickling time. Chronic and acute risk assessments revealed that dietary exposure to fluxapyroxad was within the acceptable levels from cucumber and cowpea consumption. Given high residue levels and their potential accumulation, fluxapyroxad should be continuously monitored and assessed in the future.

Keywords: Accumulation; Dissipation; Fluxapyroxad; Metabolism; Processing; Risk assessment.