Development of Y-TZP/MWCNT-SiO2 nanocomposite for dental protheses

Abstract

Y-TZP/MWCNT-SiO₂ nanocomposite was synthesized by co-precipitation and hydrothermal treatment methods. After the characterization of the MWCNT-SiO₂ powder, specimens were obtained from the synthesized material Y-TZP/MWCNT-SiO₂ by uniaxial pressing for a second characterization and later comparison of its optical and mechanical properties with the conventional Y-TZP. The MWCNT-SiO₂ was presented in bundles of carbon nanotubes coated by silica (mean length: 5.10 ± 1.34 μm /D90: 6.9 μm). The composite manufactured was opaque (contrast ratio: 0.9929 ± 0.0012) and had a white color with a slightly difference from the conventional Y-TZP (ΔE₀₀: 4.4 ± 2.2) color. The mechanical properties of Y-TZP/MWCNT-SiO₂: vickers hardness (10.14 ± 1.27 GPa; p = 0.25) and fracture toughness (4.98 ± 0.30 MPa m^1/2; p = 0.39), showed no significant difference from the conventional Y-TZP (hardness: 8.87 ± 0.89; fracture toughness: 4.98 ± 0.30 MPa m^1/2). However, for flexural strength (p = 0.003), a lower value was obtained for Y-TZP/MWCNT-SiO₂ (299.4 ± 30.5 MPa) when compared to the control Y-TZP (623.7 ± 108.8 MPa). The manufactured Y-TZP/MWCNT-SiO₂ composite presented satisfactory optical properties, however the co-precipitation and hydrothermal treatment methods need to be optimized to avoid the formation of porosities and strong agglomerates, both from Y-TZP particles and MWCNT-SiO₂ bundles, which lead to a significant decrease in the material flexural strength.

Keywords: Co-precipitation of mixed hydroxides; Hydrothermal treatment; Multi-walled carbon nanotube; Yttria-stabilized tetragonal zirconia polycrystals.