Food waste is an attractive feedstock for Anaerobic Digestion due to its high biodegradability and moisture content. Nevertheless, due to its complex structure and composition, methane yield is typically compromised with 50-60% of the theoretical maximum obtained. The well-known limitation of the hydrolysis step can be circumvented by adopting feedstock pre-treatments, such as microwave irradiation. It improves solubilization of various FW components making them more readily available for the microorganisms and reducing AD process duration. In this work different heating rates (7.8, 3.9 and 1.9 °C/min) and temperatures (85, 115, 145, 175 °C) were applied when pre-treating food waste as a substrate for AD. Increase in the solubilization of organic matter in the form of Soluble Chemical Oxygen Demand was the most significative change in FW characteristics after pre-treatment, with final temperature of 175 °C and heating rate of 3.9 °C showing a 73.19% increment. Nevertheless, process performance of AD of MW FW was optimum at 85 °C 7.8 ramp, showing no intermediate products accumulation, up to 77% more methane produced in the first week of digestion compared to the other conditions tested and reduction of 96.36% on the lag phase duration, compared to the control. On the other hand, samples treated at 175 °C, regardless of heating rate, consistently showed poor process performance, with low methane yield, possibly due to the formation of hard-to-digest compounds. This work underlines the importance of adjusting microwave temperature and power when pre-treating FW for biomethane production so the process is optimized.
Keywords: Anaerobic digestion; Biomethane; Food waste; Microwave irradiation; Pre-treament.
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