Exploring the multipotentiality of plant extracts for the green synthesis of iron nanoparticles: A study of adsorption capacity and dye degradation efficiency

Abstract

The goal of the project was to create environmentally friendly and economically viable materials for thoroughly purifying contaminated water. An affordable, phytogenic, and multifunctional plant-based nanomaterial was prepared in this context. The work demonstrates an effective green synthesis method for producing iron nanoparticles (FeNPs) using six different plant extracts as a reducing agent. The characterization of green synthesized catalysts was concluded via Spectroscopy (tauc plot), XRD, FE-SEM, and FT-IR. The produced nanomaterial, which had an X-ray diffractogram (XRD) peak at 43.33⁰ and a size range of 1.82-63.63 nm, functioned as a highly effective nano-photocatalyst for the degradation of cationic dye. Due to the presence of a lower overall secondary metabolites quota, Ocimum sanctum plant extract reduced iron precursor produced the highest yield of dried NPs, followed by Azadirachta indica, Prosopis cineraria, Syzygium cumini, Citrus limon, and Salvadora oleoides. Further, the synthesized catalyst was tested for its effectiveness against gentian violet dye degradation. Ocimum sanctum plant extract reduced iron precursor produced the highest yield of dried NPs, followed by Azadirachta indica, Prosopis cineraria, Syzygium cumini, Citrus limon, and Salvadora oleoides, in that order. The dye removal efficiency of nanoparticles was 51% (Azadirachta indica), 83% (Ocimum sanctum), 59% (Syzygium cumini), 40% (Salvadora oleoides), 59% (Prosopis cineraria), and 63% (Citrus limon) after 12 h of visible light irradiation. The key factor in the process of deterioration is •O^2-. As a result, the nanoparticles can be used in antibacterial and photocatalytic processes. The reduced band gap was responsible for the increased photocatalytic quantity. The maximum adsorption capacity at the time of equilibrium was obtained in order as Ocimum sanctum > Citrus limon > Prosopis cineraria > Syzygium cumini > Azadirachta indica > Salvadora oleoides. The simplicity of production, low cost, magnetic property, and high adsorption capacity will increase the efficacy of the water treatment method. This article reports on the creation of unique iron nanoparticles and their use in the purification of water.

Keywords: Antimicrobial activity; Antioxidant assays; Gentian violet; Green synthesis; Nanoparticle catalysts; Photocatalysis; Phytomolecules.