Fluorescence excitation-emission matrix spectroscopy coupled with parallel factor analysis to determine chlorine decay constants in urban water distribution system

Abstract

This study applied a method for estimating chlorine decay constant (k) in urban water distribution systems using fluorescence excitation-emission matrix spectroscopy-parallel factor analysis (FEEM-PARAFAC), considering that it accounts for the influence of organic matter in the target area. The simultaneous impacts of seasonal variations on chlorine consumption and dissolved organic matter (DOM) composition were investigated for a year in three full-scale water distribution systems in I city (areas S, K, and G). Bulk decay constants (kb) were obtained through bottle tests, and the kb value was observed to differ by season and significantly affected by temperature. It exhibited its highest value, 0.794 d^-1, in summer at area G. As a result of analyses through F-EEM-PARAFAC, it was determined that the components of the target raw water were humic-like and tryptophan-like. The quantitative analysis of organic substances through PARAFAC revealed that area G had the highest score (C1+C2) than other areas. 11.568, 10.578, and 11.771 in summer at areas S, K, and G, respectively. The model equations were derived such that the significant (R2 = 0.85-0.95) correlation between the C1 and C2 model scores and total chlorine decay constants (kt) verified via PARAFAC analysis of the target raw water was considered. Furthermore, a method for obtaining the wall decay constants at a target point based on the correlation equation was investigated.

Keywords: Dissolved organic matter; Fluorescence excitation emission matrix spectroscopy (F-EEM); PARAFAC; Residual chlorine; Water distribution system.