One of the potential impacts of climate change is enhanced groundwater contamination by geogenic and anthropogenic contaminants. Such impacts should be most evident in areas with high land-use change footprint. Here, we provide a novel documentation of the impact on groundwater nitrate (GWNO3 ) pollution with and without climate change in one of the most intensely groundwater-irrigated areas of South Asia (northwest India) as a consequence of changes in land use and agricultural practices at present and predicted future times. We assessed the probabilistic risk of GWNO3 pollution considering climate changes under two representative concentration pathways (RCPs), i.e., RCP 4.5 and 8.5 for 2030 and 2040, using a machine learning (Random Forest) framework. We also evaluated variations in GWNO3 distribution against a no climate change (NCC) scenario considering 2020 status quo climate conditions. The climate change projections showed that the annual temperatures would rise under both RCPs. The precipitation is predicted to rise by 5% under RCP 8.5 by 2040, while it would decline under RCP 4.5. The predicted scenarios indicate that the areas at high risk of GWNO3 pollution will increase to 49 and 50% in 2030 and 66 and 65% in 2040 under RCP 4.5 and 8.5, respectively. These predictions are higher compared to the NCC condition (43% in 2030 and 60% in 2040). However, the areas at high risk can decrease significantly by 2040 with restricted fertilizer usage, especially under the RCP 8.5 scenario. The risk maps identified the central, south, and southeastern parts of the study area to be at persistent high risk of GWNO3 pollution. The outcomes show that the climate factors may impose a significant influence on the GWNO3 pollution, and if fertilizer inputs and land uses are not managed properly, future climate change scenarios can critically impact the groundwater quality in highly agrarian areas.
© 2022 The Authors. Published by American Chemical Society.