Cationic dialdehyde cellulose microfibers for efficient removal of eriochrome black T from aqueous solution

Bioresour Technol. 2023 Jul:380:129096. doi: 10.1016/j.biortech.2023.129096. Epub 2023 Apr 24.

Abstract

Materials based on cellulose have been widely used as a decontaminant agent of wastewater. However, it can not be found in the literature any application of the cationic dialdehyde cellulose (cDAC) in anionic dye removal. Therefore, this study aims a circular economy concept using sugarcane bagasse to obtain a functionalized cellulose by oxidation and cationization. cDAC was characterized by SEM, FT-IR, oxidation degree, and DSC. Adsorption capacity was evaluated by pH, kinetic, concentration effect, strength ionic tests, and recycling. The kinetic followed Elovich model (R2 = 0.92605 for EBT = 100 mg/L) and non-linear Langmuir model (R2 = 0.94542), which resulted in a maximum adsorption capacity of 563.30 mg/g. The cellulose adsorbent reached an efficient recyclability of 4 cycles. Thus, this work presents a potential material to become a new, clean, low-cost, recyclable, and environmentally friendly alternative for effluent decontamination-containing dyes.

Keywords: Adsorption; Biosorbents; Cationic Dialdehyde Cellulose; Eriochrome Black T; Microfibers.

MeSH terms

  • Adsorption
  • Cations / chemistry
  • Cellulose / chemistry
  • Coloring Agents / chemistry
  • Kinetics
  • Saccharum* / chemistry
  • Spectroscopy, Fourier Transform Infrared
  • Water Pollutants, Chemical* / chemistry

Substances

  • 2,3-dialdehydocellulose
  • Cellulose
  • chlorambucil-docosahexaenoic acid conjugate
  • Eriochrome Black T
  • Coloring Agents
  • Cations
  • Water Pollutants, Chemical