Mechanical, chemical, and bio-recycling of biodegradable plastics: A review

Abstract

The extensive use of petroleum-based non-biodegradable plastics for various applications has led to global concerns regarding the severe environmental issues associated with them. However, biodegradable plastics are emerging as green alternatives to petroleum-based non-biodegradable plastics. Biodegradable plastics, which include bio-based and petroleum-based biodegradable polymers, exhibit advantageous properties such as renewability, biocompatibility, and non-toxicity. Furthermore, certain biodegradable plastics are compatible with existing recycling streams intended for conventional plastics and are biodegradable in controlled and/or predicted environments. Recycling biodegradable plastics before their end-of-life (EOL) degradation further enhances their sustainability and reduces their carbon footprint. Since the production of biodegradable plastic is increasing and these materials will coexist with conventional plastics for many years to come, it is essential to identify the optimal recycling options for each of the most prevalent biodegradable plastics. The substitution of virgin biodegradable plastics by their recyclates leads to higher savings in the primary energy demand and reduces global warming impact. This review covers the current state of the mechanical, chemical, and bio-recycling of post-industrial and post-consumer waste of biodegradable plastics and their related composites. The effects of recycling on the chemical structure and thermomechanical properties of biodegradable plastics are also reported. Additionally, the improvement of biodegradable plastics by blending them with other polymers and nanoparticles is comprehensively discussed. Finally, the status of bioplastic usage, life cycle assessment, EOL management, bioplastic market, and the challenges associated with the recyclability of biodegradable plastics are addressed. This review gives comprehensive insights into the recycling processes that may be employed for the recycling of biodegradable plastics.

Keywords: Biodegradable Plastics; Bioplastic Market; Life cycle assessment; Recycling.