Nanoreactors consisting of hydrophilic porous SiO2 shells and amphiphilic copolymer cores have been prepared, which can easily self-tune their hydrophilic/hydrophobic balance depending on the environment and exhibit chameleon-like behavior. The accordingly obtained nanoparticles show excellent colloidal stability in a variety of solvents with different polarity. Most importantly, thanks to the assistance of the nitroxide radicals attached to the amphiphilic copolymers, the synthesized nanoreactors show high catalytic activity for model reactions in both polar and nonpolar environments and, more particularly, realize a high selectivity for the products resulting from the oxidation of benzyl alcohol in toluene.
Keywords: amphiphilic polymers; chameleon-like behavior; core−shell nanoparticles; multienvironment nanoreactors; self-regulation.