Microstructure Evolution and Mechanical Properties of Al-Cu-Mg Alloys with Si Addition

Materials (Basel). 2023 Mar 30;16(7):2783. doi: 10.3390/ma16072783.

Abstract

The aim of this study was to investigate the impact of the addition of a minor quantity of Si on the microstructure evolution, heat treatment response, and mechanical properties of the Al-4.5Cu-0.15Ti-3.0Mg alloy. The microstructure analysis of the base alloy revealed the presence of α-Al grains, eutectic α-Al-Al2CuMg (S) phases, and Mg32(Al, Cu)49 (T) phases within the Al grains. In contrast, the Si-added alloy featured the eutectic α-Al-Mg2Si phases, eutectic α-Al-S-Mg2Si, and Ti-Si-based intermetallic compounds in addition to the aforementioned phases. The study found that the Si-added alloy had a greater quantity of T phase in comparison to the base alloy, which was attributed to the promotion of T phase precipitation facilitated by the inclusion of Si. Additionally, Si facilitated the formation of S phase during aging treatment, thereby accelerating the precipitation-hardening response of the Si-added alloy. The as-cast temper of the base alloy displayed a yield strength of roughly 153 MPa, which increased to 170 MPa in the Si-added alloy. As a result of the aging treatment, both alloys exhibited a notable increase in tensile strength, which was ascribed to the precipitation of S phases. In the T6 temper, the base alloy exhibited a yield strength of 270 MPa, while the Si-added alloy exhibited a significantly higher yield strength of 324 MPa. This novel Si-added alloy demonstrated superior tensile properties compared to many commercially available high-Mg-added Al-Cu-Mg alloys, making it a potential replacement for such alloys in various applications within the aerospace and automotive industries.

Keywords: Al–Cu–Mg alloy; Si addition; heat treatment; microstructure; tensile properties.