Investigation of Stress Corrosion Cracking Resistance of Irradiated 12Cr Ferritic-Martensitic Stainless Steel in Supercritical Water Environment

Materials (Basel). 2023 Mar 24;16(7):2585. doi: 10.3390/ma16072585.

Abstract

The supercritical water-cooled reactors (SWCR) belong to Generation IV of reactors. These reactors have a number of advantages over currently operating WWERs and PWRs. These advantages include higher thermal efficiency, a more simplified unit design, and the possibility of incorporating it into a closed fuel cycle. It is therefore necessary to identify candidate materials for the SWCR and validate the safety and effectiveness of their use. 12Cr ferritic-martensitic (F/M) stainless steel is considered a candidate material for SWCR internals. Radiation embrittlement and corrosion cracking in the primary circuit coolant environment are the main mechanisms of F/M steels degradation during SWCR operation. Here, the stress corrosion cracking (SCC) in supercritical water at 390 and 550 °C of 12Cr F/M steel irradiated by neutrons to 12 dpa is investigated. Autoclave tests of specially designed disk specimens in supercritical water were performed. The tests were carried out under different constant load (CL), temperature 450 °C, and pressure in autoclave 25 MPa. The threshold stress, below which the SCC initiation of irradiated 12Cr F/M steel does not occur, was determined.

Keywords: constant load test; ferritic-martensitic stainless steel; microcleavage fracture; neutron irradiation; oxide layer; stress corrosion cracking; supercritical water-cooled reactors.

Grants and funding

This work was supported financially by the State Corporation “Rosatom” under the state contract № N.4sch.241.09.22.1130 in the framework of the national project “Development of Equipment, Technologies and Scientific Research in the Field of Nuclear Energy Use in the Russian Federation until 2024”.