Enhanced Performance of WO3/SnO2 Nanocomposite Electrodes with Redox-Active Electrolytes for Supercapacitors

Abstract

For effective supercapacitors, we developed a process involving chemical bath deposition, followed by electrochemical deposition and calcination, to produce WO₃/SnO₂ nanocomposite electrodes. In aqueous solutions, the hexagonal WO₃ microspheres were first chemically deposited on a carbon cloth, and then tin oxides were uniformly electrodeposited. The synthesized WO₃/SnO₂ nanocomposite was characterized by XRD, XPS, SEM, and EDX techniques. Electrochemical properties of the WO₃/SnO₂ nanocomposite were analyzed by cyclic voltammetry, galvanostatic charge-discharge tests, and electrochemical impedance spectroscopy in an aqueous solution of Na₂SO₄ with/without the redox-active electrolyte K₃Fe(CN)₆. K₃Fe(CN)₆ exhibited a synergetic effect on the electrochemical performance of the WO₃/SnO₂ nanocomposite electrode, with a specific capacitance of 640 F/g at a scan rate of 5 mV/s, while that without K₃Fe(CN)₆ was 530 F/g. The WO₃/SnO₂ nanocomposite catalyzed the redox reactions of [Fe(CN)₆]³/[Fe(CN)₆]^4- ions, and the [Fe(CN)₆]^3-/[Fe(CN)₆]^4- ions also promoted redox reactions of the WO₃/SnO₂ nanocomposite. A symmetrical configuration of the nanocomposite electrodes provided good cycling stability (coulombic efficiency of 99.6% over 2000 cycles) and satisfied both energy density (60 Whkg^-1) and power density (540 Wkg^-1) requirements. Thus, the WO₃/SnO₂ nanocomposite prepared by this simple process is a promising component for a hybrid pseudocapacitor system with a redox-flow battery mechanism.

Keywords: energy storage; nanocomposite; redox-additive; supercapacitor; tin oxide; tungsten oxide.