Pore Structure and Adsorption Characteristics of Maceral Groups: Insights from Centrifugal Flotation Experiment of Coals

TengFei Jia; Songhang Zhang; Shuheng Tang; Di Xin; Qian Zhang; Ke Zhang

doi:10.1021/acsomega.2c07876

Pore Structure and Adsorption Characteristics of Maceral Groups: Insights from Centrifugal Flotation Experiment of Coals

ACS Omega. 2023 Mar 21;8(13):12079-12097. doi: 10.1021/acsomega.2c07876. eCollection 2023 Apr 4.

Authors

TengFei Jia^{1

2

3}, Songhang Zhang^{1

2

3}, Shuheng Tang^{1

2

3}, Di Xin^{1

2

3}, Qian Zhang^{1

2

3}, Ke Zhang^{1

2

3}

Affiliations

¹ Institute of Energy Resources, China University of Geosciences, Beijing 100083, China.
² Key Laboratory of Marine Reservoir Evolution and Hydrocarbon Enrichment Mechanism, Ministry of Education, China University of Geosciences, Beijing 100083, China.
³ Coal Reservoir Laboratory of National Engineering Research Center of CBM Development & Utilization, China University of Geosciences, Beijing 100083, China.

Abstract

Coal has various types of macerals, which have different pore structures and adsorption properties that change with coal's thermal metamorphism. In-depth study of the characteristics of different coal macerals, especially the pore structure and adsorption properties, can better predict the coal reservoir gas storage capacity and migration ability. In this study, the sub-samples enriched in a specific maceral group with different coal ranks and particle sizes were obtained by centrifugal flotation experiments. Then, experiments containing low-temperature N₂ isotherm adsorption (LT-N₂GA), low-temperature CO₂ isotherm adsorption (LT-CO₂GA), and methane isothermal adsorption were carried out on the sub-samples to quantitatively analyze the evolution characteristics of pore structure and adsorption properties of different maceral groups. The results showed the following: (1) The separation effect of the light maceral groups by centrifugal flotation experiments increased with the decrease of particle sizes, which were treated with the heavy liquid of low and medium densities, while that of the heavy maceral groups had the relatively best separation effect in the particle sizes of 0.1-0.125 mm, which were treated with the heavy liquid of high densities. (2) The vitrinite-enriched samples had more ultra-micropores (mainly within the diameter range of 0.4-0.65 nm), while the inertinite enriched samples had more mesopores and transition pores (mainly within the diameter range of 40-50 nm). (3) For the low-rank coal, inertinite had more potential methane adsorption capacity. However, for the medium- and high-rank coal, vitrinite had more potential methane adsorption capacity. (4) For the low-rank coal, the adsorption potential and adsorption space increased with the increase of the inertinite content, while the adsorption potential, adsorption space, and surface free energy for the medium- and high-rank coal increased with the increase of vitrinite content. It is expected that the results can deepen the understanding about the gas storage capacity and migration ability and be used in the prevention of gas outburst and the reduction of carbon emission.