The acidizing corrosion inhibitors reported so far have a poor effect on duplex stainless steel in high-temperature and high-concentration acid systems and cannot effectively inhibit the occurrence of selective corrosion. In this paper, a new acidizing corrosion inhibitor was designed, which was mainly composed of Mannich base and antimony salt. The inorganic substance in the corrosion inhibitor had good stability at high temperatures and could quickly form a complex with the metal matrix to enhance the binding ability. The organic substance can make up for the non-dense part of the inorganic film. The properties of developed corrosion inhibitors were analyzed by quantum chemical calculation, molecular dynamics simulation, and scanning electron microscopy. The results showed that a double-layer membrane structure could be constructed after adding the corrosion inhibitor, which could play a good role in blocking the diffusion of acid solution at high-temperature. The uniform corrosion rate of 2205 duplex stainless steel after adding acidizing corrosion inhibitor immersion in a simulated service condition (9 wt.% HCl + 1.5 wt.% HF + 3 wt.% CH3COOH + 4~6 wt.%) at 140 °C, 160 °C and 180 °C for a 4 h test is 6.9350 g·m-2·h-1, 6.3899 g·m-2·h-1 and 12.1881 g·m-2·h-1, respectively, which shows excellent corrosion inhibition effect and is far lower than that of the commonly accepted 81 g·m-2·h-1 and no selective corrosion could be detected.
Keywords: corrosion inhibitor; duplex stainless steel; high-temperature acidification; molecular dynamics simulation; selective corrosion.