In this work, prepared nanoparticle samples of Ni1-xCrx with a fixed ratio of platinum (3%) were synthesized and loaded onto carbon nanofibers, which were produced by an electrospinning technique and carbonized at 900 °C for 7 h in an argon atmosphere. A variety of analysis techniques were applied to examine the stoichiometry, structure, surface morphology, and electrochemical activity. The carbonization process produces carbon nanofibers decorated with metal nanoparticles. Typical fibre diameters are 250-520 nm. The fibre morphologies of the treated samples don't exhibit any overt alterations. A study of the samples' methanol electrocatalytic capabilities was conducted. Cyclic voltammetry, chronoamperometry, and electrochemical impedance measurements were used to investigate catalytic performance and electrode stability as a function of electrolyte concentration, scan rate, and reaction time. The electrooxidation reaction's activation energy is increased, and the electrode's stability is increased, when Cr is added to Ni. In sample C3, the maximum current density (JPE) was 170.3 mA/cm2 at 0.8 V with an onset potential of 0.352 V. Utilizing our electrocatalysts, the electrooxidation of methanol involves a mix of kinetic and diffusion control limiting reactions. This study has shown how to fabricate a powerful Ni-Pt-Cr-based methanol electrooxidation catalyst using a novel approach.
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