In this Letter, we present a compact scattering spectrometer system based on fluorosilicate glass ceramics. By the algorithmic spectral calibration and reconstruction, we achieve wavelength detection with a resolution of 0.1 nm. Numerous nanocrystals embedded in the glass host in the glass ceramics result in a significant natural multilayer scattering medium, which can provide a 60% scattering efficiency for incident light while increasing the optical path of incident light transmitting in the medium. The glass ceramics scattering medium with a rather compact physical size is integrated with a low-cost camera to compose an optical spectral system, which has potential application in lab-on-a-chip optical spectroscopy.