Characterization of ionic liquids removing heavy metals from electroplating sludge: Influencing factors, optimisation strategies and reaction mechanisms

Abstract

The disposal of electroplating sludge (ES) is a common concern of researchers. Currently, it is difficult to achieve effective fixation of heavy metals (HMs) using traditional ES treatment. As green and effective HMs removal agents, ionic liquids can be used for the disposal of ES. In this study, 1-butyl-3-methyl-imidazole hydrogen sulphate ([Bmim]HSO₄) and 1-propyl sulphonic acid-3-methyl imidazole hydrogen sulphate ([PrSO₃Hmim]HSO₄) were used as washing solvents for the removal of Cr, Ni, and Cu from ES. In reaction with increased agent concentration, solid-liquid ratio, and duration, the amount of HMs eliminated from ES rises, whereas opposite patterns were shown in response to rising pH. The quadratic orthogonal regression optimisation analysis also revealed that the ideal washing specifications for [Bmim]HSO₄ were 60 g L^-1, 1:40, and 60 min, respectively, for agent concentration, solid-liquid ratio, and washing time, while those for [PrSO₃Hmim]HSO₄ were 60 g L^-1, 1:35, and 60 min, respectively. Under the optimal experimental conditions, the Cr, Ni, and Cu removal efficiencies for [Bmim]HSO₄ were 84.3, 78.6, and 89.7%, respectively, and those values for [PrSO₃Hmim]HSO₄ were 99.8, 90.1, and 91.3%, respectively. This was mainly attributed to that ionic liquids enhance metal desorption through acid solubilisation, chelation, and electrostatic attraction. Overall, ionic liquids are reliable washing reagents for ES contaminated by HMs.

Keywords: Electroplating sludge; Environmental risk; Heavy metals; Ionic liquids.