Rapid adsorption of directional cellulose nanofibers/3-glycidoxypropyltrimethoxysilane/polyethyleneimine aerogels on microplastics in water

Int J Biol Macromol. 2023 Apr 30:235:123884. doi: 10.1016/j.ijbiomac.2023.123884. Epub 2023 Mar 2.

Abstract

Currently, cellulose-based aerogel materials are a hot topic owing to their high specific surface area and high porosity, as well as the green, degradable and biocompatible characteristics of cellulosic materials. Modification of cellulose to enhance the adsorption properties of cellulose-based aerogels has important research significance in solving the problem of water body pollution. In this paper, cellulose nanofibers (CNFs) were modified with polyethyleneimine (PEI), and modified aerogels with directional structures were prepared by a simple reaction and freeze-drying method. The adsorption behavior of the aerogel followed the adsorption kinetic models and isotherm models. More significantly, the aerogel could rapidly adsorb microplastics, reaching equilibrium within 20 min. Furthermore, the fluorescence displayed directly expresses the occurrence of the adsorption behavior of the aerogels. Therefore, the modified cellulose nanofiber aerogels were of reference significance for microplastic removal from water bodies.

Keywords: Fluorescence; Rapid adsorption; Removal of microplastics.

MeSH terms

  • Adsorption
  • Cellulose / chemistry
  • Microplastics
  • Nanofibers* / chemistry
  • Plastics
  • Polyethyleneimine
  • Water / chemistry

Substances

  • Microplastics
  • Plastics
  • Polyethyleneimine
  • Water
  • 3-glycidoxypropyltrimethoxysilane
  • Cellulose