The lack of freshwater has been threatening many people who are living in Africa, the Middle East, and Oceania, while the discovery of freshwater harvesting technology is considered a promising solution. Recent advances in structured surface materials, metal-organic frameworks, hygroscopic inorganic compounds (and derivative materials), and functional hydrogels have demonstrated their potential as platform technologies for atmospheric water (i.e., supersaturated fog and unsaturated water) harvesting due to their cheap price, zero second energy requirement, high water capture capacity, and easy installation and operation compared with traditional water harvesting methods, such as long-distance water transportation, seawater desalination, and electrical dew collection devices in rural areas or individual-scale emergent usage. In this contribution, we highlight recent developments in functional materials for "passive" atmospheric water harvesting application, focusing on the structure-property relationship (SPR) to illustrate the transport mechanism of water capture and release. We also discuss technical challenges in the practical applications of the water harvesting materials, including low adaptability in a harsh environment, low capacity under low humidity, self-desorption, and insufficient solar-thermal conversion. Finally, we provide insightful perspectives on the design and fabrication of atmospheric water harvesting materials.
© 2022 The Authors. Published by American Chemical Society.