Human-Centric Lighting: Rare-Earth-Free Photoluminescent Materials for Correlated Color Temperature Tunable White LEDs

Int J Mol Sci. 2023 Feb 10;24(4):3602. doi: 10.3390/ijms24043602.

Abstract

Artificial lighting is ubiquitous in modern society, with detrimental effects on sleep and health. The reason for this is that light is responsible not only for vision but also for non-visual functions, such as the regulation of the circadian system. To avoid circadian disruption, artificial lighting should be dynamic, changing throughout the day in a manner comparable to natural light in terms of both light intensity and associated color temperature. This is one of the main goals of human-centric lighting. Regarding the type of materials, the majority of white light-emitting diodes (WLEDs) make use of rare-earth photoluminescent materials; therefore, WLED development is at serious risk due to the explosive growth in demand for these materials and a monopoly on sources of supply. Photoluminescent organic compounds are a considerable and promising alternative. In this article, we present several WLEDs that were manufactured using a blue LED chip as the excitation source and two photoluminescent organic dyes (Coumarin 6 and Nile Red) embedded in flexible layers, which function as spectral converters in a multilayer remote phosphor arrangement. The correlated color temperature (CCT) values range from 2975 K to 6261 K, while light quality is preserved with chromatic reproduction index (CRI) values superior to 80. Our findings illustrate for the first time the enormous potential of organic materials for supporting human-centric lighting.

Keywords: circadian rhythms; human-centric lighting; photoluminescent organic materials; rare-earth-free materials; spectral conversion; tunable spectrum of WLEDs.

MeSH terms

  • Coloring Agents
  • Commerce
  • Humans
  • Light
  • Lighting*
  • Metals, Rare Earth*
  • Temperature

Substances

  • Coloring Agents
  • Metals, Rare Earth

Grants and funding

This research and the APC were funded by FICYT—Consejería de Ciencia, Innovación y Universidad—Gobierno del Principado de Asturias through the 2018–2022 Science, Technology and Innovation Plan and by the European Union through the European Regional Development Fund (ERDF). Grant number AYUD/2022/57246.