Improved analysis of THz metamaterials for glucose sensing based on modified Lorentz dispersion model

Spectrochim Acta A Mol Biomol Spectrosc. 2023 May 15:293:122519. doi: 10.1016/j.saa.2023.122519. Epub 2023 Feb 18.

Abstract

Resonant structures, such as metamaterials, which can focus electromagnetic fields on a localized spot, are essential to perform label-free detection with high sensitivity in the terahertz (THz) range. Moreover, the refractive index (RI) of a sensing analyte is the most important aspect in the optimization of the characteristics of a highly sensitive resonant structure. However, in previous studies, the sensitivity of metamaterials was calculated while considering the RI of an analyte as a constant value. Consequently, the result for a sensing material with a specific absorption spectrum was inaccurate. To solve this problem, this study developed a modified Lorentz model. Split-ring resonator-based metamaterials were fabricated to verify the model, and the glucose-sensing range from 0 to 500 mg/dL was measured using a commercial THz time-domain spectroscopy system. In addition, a finite-difference time-domain simulation was implemented based on the modified Lorentz model and fabrication design of the metamaterials. The calculation results were compared with the measurement results and were found to be consistent.

Keywords: Glucose; Lorentz model; Metamaterials; Spectroscopy; Split-ring resonator; Terahertz.