Adsorption mechanism of Cr(VI) on woody-activated carbons

Hua Wang; Wencheng Wang; Song Zhou; Xuchun Gao

doi:10.1016/j.heliyon.2023.e13267

Adsorption mechanism of Cr(VI) on woody-activated carbons

Heliyon. 2023 Jan 26;9(2):e13267. doi: 10.1016/j.heliyon.2023.e13267. eCollection 2023 Feb.

Authors

Hua Wang^{1

2}, Wencheng Wang¹, Song Zhou¹, Xuchun Gao^{1

2}

Affiliations

¹ College of Chemistry and Chemical Engineering, Yulin City, 719000, China.
² Shaanxi Provincial Key Laboratory of Clean Utilization of Low-Modified Coal, Yulin City, 719000, China.

Abstract

To provide guidance for the selection of woody-activated carbon in the treatment of wastewater containing hexavalent chromium (Cr(VI)), the adsorption tests on two varieties of commercial woody-activated carbon powder from different manufacturers were carried out. The physicochemical properties and structural characteristics of activated carbon were studied by using elemental, chemical, and instrumental analyses. The adsorption mechanism of Cr(VI) was discussed by investigating the factors affecting the removal of hexavalent chromium. The two kinds of woody-activated carbon have microporous and mesoporous structures. Commercial woody-activated carbon No.1 (ACI) has a more extensive specific surface area and a better-developed pore structure. While ACI exhibits a higher adsorption capability when the content of Cr(VI) is high, commercial woody-activated carbon No.2 (AC) can remove hexavalent chromium fast when the concentration is low. A rise in pH value is not helpful for the materials to remove Cr(VI) from solutions. For Cr(VI) removal, the optimum pH value is 2. The adsorption of Cr(VI) by AC and ACI followed the pseudo-second-order kinetic model and Langmuir isothermal adsorption equation. The maximum adsorption value of Cr(VI) is 154.56 mg/g for AC and 241.55 mg/g for ACI. There is chemical adsorption during the Cr(VI) removal. A lot of Cr (Ⅲ) was formed by Cr(VI). The abundance of pores and the reducing ability of the materials are essential for the removal of Cr(VI).

Keywords: Adsorption mechanism; Cr(VI) removal; Isotherm; Kinetic; Woody-activated carbon.