Metal-organic frameworks/cellulose hybrids with their modern technological implementation towards water treatment

Abstract

Metal-organic frameworks (MOFs) are amongst the most attractive porous polymeric networks with appealing properties. However, their inherent fragility, powder nature, low processibility, and handling present some exceptional challenges for high-tech commercial applications. Currently, economic and environmental concerns drive the development of some bioinspired polymeric matrices containing MOFs. As an artifact, the availability of previously unattainable properties is negotiated by conjugating cellulosic materials with crystalline MOFs. Thus, multi-dimensional organic-inorganic hybrid composites are formed with high electrical, optical, mechanical, and thermal features. These MOF/cellulose hybrids, known as CelloMOFs (cellulose MOFs), have remarkable mechanical properties with tunable porosities, specific surface area and accessible active sites, making them ideal for real-world troubleshooting applications such as wastewater treatment, chemical sensing, energy storage, and so on. In this review, current state-of-the-art strategic synthesis routes for fabrication of MOF/cellulose composites with a specific focus on CelloMOFs as a potential tool for mitigation of the targeted emerging water contaminants have been done under the same umbrella, which has previously been less explored. Streamlining discussions on general properties such as raw material selection, structural analysis of cellulose, availability of surface functional groups, cellulose-metal node interactions, cellulose charging, and so on have been emphasized, as has integration with robust MOFs. A better understanding of these fundamental properties is critical because they will have a significant impact on the performance of MOF/cellulose composites in a variety of applications. Furthermore, at the end of this review, the challenges and perspectives of using CelloMOFs have been discussed in a concise manner in order to improve their practical utility rather than just concept mapping.

Keywords: Biocompatible; Cellulose; Metal organic frameworks (MOFs); Organic-inorganic hybrid composite; Water remediation.