Violuric acid carbon dots as a highly fluorescence probe for ultrasensitive determination of Zn (II) in tomato paste

Abstract

Zinc is an essential metal since it plays an important role in biological systems, therefore, determination of zinc in food samples is important. Violuric acid was used to prepare highly fluorescent carbon dots (CDs), when it irradiated with ultraviolet radiation at 365 nm, a strong violet fluorescence was observed which caused by the increased amount of nitrogen in the CD structure, which were then successfully used for sensing zinc ion based on quenching of fluorescence. Violuric acid's hydrothermal carbonization reaction's temperature and time were simply optimized for better-quality performance of the CDs as-synthesized. The probe was characterized by HRTEM, SEM, XRD, EDX, fluorescence, UV-Visible absorption spectrophotometry, and FTIR. With a lower LOD 0.32 nM, the developed approach demonstrates an exceptional sensitivity and good selective response to the Zn²⁺ at 25℃. Compared to the results from ICP, the sensor was successfully used for determination of Zn²⁺ ions in tomato paste samples.

Keywords: Fluorescent nanomaterial; New carbon dots; Tomato paste; Violuric acid; Zinc ion.