Review of the application of surfactants in microemulsion systems for remediation of petroleum contaminated soil and sediments

Environ Sci Pollut Res Int. 2023 Mar;30(12):32168-32183. doi: 10.1007/s11356-023-25622-4. Epub 2023 Feb 1.

Abstract

Microemulsions are important for soil and sediment remediation technology. The characteristics of the surfactants that make up these microemulsions include low sorption into soil or sediments, low surface and interfacial tension, the ability to penetrate tiny pores, and good solubilization of contaminants. This review revealed that microemulsions formulated with nonionic and anionic surfactants have higher recovery efficiencies for hydrophobic contaminants than cationic ones, as evidenced by the surveyed studies reporting effective remediation of soils and sediments using on microemulsions. These microemulsified systems have been found to remove petroleum and its derivatives from soil or sediments at percentages ranging from 40 to 100%. As such, this review can aid with the choice of surfactants used in microemulsions for remediation, such as those with plant-based components, which are promising solutions for the remediation of contaminated soils due to their contaminant extraction efficiency and biodegradability.

Keywords: Anionic and nonionic surfactants; Microemulsions; Petroleum; Remediation; Removal of organic contaminants; Soil and sediment washing.

Publication types

  • Review

MeSH terms

  • Environmental Pollution
  • Petroleum*
  • Soil
  • Soil Pollutants* / analysis
  • Surface-Active Agents / chemistry

Substances

  • Surface-Active Agents
  • Soil
  • Petroleum
  • Soil Pollutants