Evaporation-induced fractal patterns: A bridge between uniform pattern and coffee ring

Abstract

Hypothesis: The rich variety of patterns induced by evaporating drops containing particles has significant guidance for coating processes, inkjet printing, and nanosemiconductors. However, most existing works construct a uniform pattern by suppressing the coffee ring effect, and establishing the connection between them is still an academic challenge.

Experiments: We report uniform, polygonal, and coffee ring patterns obtained by adjusting the solute concentration that sets in when an ethanol drop with dissolved ibuprofen is deposited on a silicon wafer.

Findings: Pattern formation involves rich hydrodynamic events: spreading, evaporative instability, dewetting, film formation, and particle deposition. Based on the distinct multiscale properties, this series of patterns is directly connected from the perspective of fractal geometry, which allows us to name them "fractal deposition patterns". A theoretical model considering film stability is established to explain the mechanism behind pattern formation, which is well verified by experiments. This work has presented a unique strategy that can directly connect uniform, polygonal, and coffee ring patterns under the same physics, hoping to provide instructive guidance for practical applications.

Keywords: Contact line; Drop; Evaporation; Film stability; Self-assembled pattern.