Modification of Hollow Expanded Microspheres with Superior Thermal Insulation Properties and Their Applications

Chem Asian J. 2023 Mar 14;18(6):e202201233. doi: 10.1002/asia.202201233. Epub 2023 Feb 6.

Abstract

Thermally expandable microspheres (TEMs) are hollow polymeric particles in which a blowing gas has been encapsulated. This property makes them excellent for thermal insulation applications, such as lightweight fillers. This study has developed a viable technology for further improving thermal insulation properties in the field that needs excellent thermal insulation of textile fabrics. The ATO/TEMs composites were designed and prepared to reduce sunlight radiation by the charge gravity method. The test results showed that the ATO-coated TEMs effectively block thermal radiation from sunlight. The temperature difference between ATO/TEMs treated cotton and the uncoated cotton fabric was 9 °C, and the thermal conductivity coatings were 0.0432 W/m⋅K. The UPF value of ATO/TEMs (ILs) coated cotton fabric is 440, significantly higher than pure cotton. This approach can provide insight into the design of high-performance solar insulation composite structures.

Keywords: Antimony Tin Oxide; Hollow thermally expanded microspheres; Infrared absorption; Multifunctional coating; Thermal insulation.