Yolk-shell nanoparticles (YSNs) have attracted a broad interest in the field of catalysis due to their unique structure and properties. The hollow structure of YSNs brings high porosity and specific surface areas which is conducive to the catalytic reactions. The flexible tailorability and functionality of both the cores and shells allow a rational design of the catalyst and may have synergistic effect which will improve the catalytic performance. Herein, an overview of the research progress with respect to the synthesis and catalytic applications of YSNs is provided. The major strategies for the synthesis of YSNs are presented, including hard template method, soft template method, ship-in-a-bottle method, galvanic replacement method, Kirkendall diffusion method as well as the Ostwald ripening method. Moreover, we discuss in detail the recent progress of YSNs in catalytic applications including chemical catalysis, photocatalysis and electrocatalysis. Finally, the future research and development of YSNs are prospected.
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