Electrochemical organic reactions: A tutorial review

Front Chem. 2023 Jan 10:10:956502. doi: 10.3389/fchem.2022.956502. eCollection 2022.

Abstract

Although the core of electrochemistry involves simple oxidation and reduction reactions, it can be complicated in real electrochemical organic reactions. The principles used in electrochemical reactions have been derived using physical organic chemistry, which drives other organic/inorganic reactions. This review mainly comprises two themes: the first discusses the factors that help optimize an electrochemical reaction, including electrodes, supporting electrolytes, and electrochemical cell design, and the second outlines studies conducted in the field over a period of 10 years. Electrochemical reactions can be used as a versatile tool for synthetically important reactions by modifying the constant electrolysis current.

Keywords: CO2 reduction; electrocatalysis; electrochemical techniques and methods; kinetics; organic reaction.

Publication types

  • Review