Magnetic sustentation as an adsorption characterization technique for paramagnetic metal-organic frameworks

Nagore Barroso; Jacopo Andreo; Garikoitz Beobide; Oscar Castillo; Antonio Luque; Sonia Pérez-Yáñez; Stefan Wuttke

doi:10.1038/s42004-022-00799-w

Magnetic sustentation as an adsorption characterization technique for paramagnetic metal-organic frameworks

Commun Chem. 2023 Jan 5;6(1):4. doi: 10.1038/s42004-022-00799-w.

Authors

Nagore Barroso¹, Jacopo Andreo¹, Garikoitz Beobide^{1

2}, Oscar Castillo^{3

4}, Antonio Luque^{1

2}, Sonia Pérez-Yáñez^{1

2}, Stefan Wuttke^{5

6}

Affiliations

¹ BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48950, Leioa, Spain.
² Organic and Inorganic Chemistry Department, University of the Basque Country, UPV/EHU, Barrio Sarriena s/n, 48950, Leioa, Spain.
³ BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48950, Leioa, Spain. oscar.castillo@ehu.eus.
⁴ Organic and Inorganic Chemistry Department, University of the Basque Country, UPV/EHU, Barrio Sarriena s/n, 48950, Leioa, Spain. oscar.castillo@ehu.eus.
⁵ BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48950, Leioa, Spain. stefan.wuttke@bcmaterials.net.
⁶ IKERBASQUE, Basque Foundation for Science, 48009, Bilbao, Spain. stefan.wuttke@bcmaterials.net.

Abstract

Nowadays, there are many reliable characterization techniques for the study of adsorption properties in gas phase. However, the techniques available for the study of adsorption processes in solution, rely on indirect characterization techniques that measure the adsorbate concentration remaining in solution. In this work, we present a sensing method based on the magnetic properties of metal-organic frameworks (MOFs) containing paramagnetic metal centres, which stands out for the rapidity, low cost and in situ direct measurement of the incorporated adsorbate within the porous material. To illustrate this sensing technique, the adsorption in solution of four MOFs have been characterized: MIL-88A(Fe), MOF-74(Cu, Co) and ZIF-67(Co). Our simple and efficient method allows the direct determination of the adsorbed mass, as well as the measurement of adsorption isotherm curves, which we hope will greatly advance the study of adsorption processes in solution, since this method is independent of the chemical nature of the adsorbate that often makes its quantification difficult.