Hydrogen has the potential to be one of the solutions that can address environmental pollution and greenhouse emissions from traditional fossil fuels. However, high costs hinder its large-scale commercialization, particularly for enabling devices such as proton exchange membrane fuel cells (PEMFCs). The precious metal Pt is indispensable in boosting the oxygen reduction reaction (ORR) in cathode electrocatalysts from the most crucial component, i.e., the membrane electrode assembly (MEA). MEAs account for a considerable amount of the entire cost of PEMFCs. To address these bottlenecks, researchers either increase Pt utilization efficiency or produce MEAs with enhanced performance but less Pt. Only a few reviews that explain the approaches are available. This review summarizes advances in designing nanocatalysts and optimizing the catalyst layer structure to achieve low-Pt loading MEAs. Different strategies and their corresponding effectiveness, e.g., performance in half-cells or MEA, are summarized and compared. Finally, future directions are discussed and proposed, aiming at affordable, highly active, and durable PEMFCs.
Keywords: electrocatalysts; membrane electrode assembly; nanocatalysts; oxygen reduction reaction; proton exchange membrane fuel cells.