Solar photocatalytic disinfection of real municipal wastewater using highly durable TiO2-coated composite in a pilot scale once through reactor

Environ Sci Pollut Res Int. 2023 Mar;30(15):43654-43664. doi: 10.1007/s11356-023-25331-y. Epub 2023 Jan 20.

Abstract

Pollution of water sources by pathogens is a significant concern worldwide. In the present study, a pilot-scale once-through reactor was fabricated to investigate bacteria's inactivation and the degradation of organic matter present in municipal wastewater using an iron-mediated TiO2 catalyst in fixed mode. The catalyst was fabricated (in a spherical shape) using waste material such as foundry sand and fly ash and coated with TiO2 for a combined hybrid effect. The influence of H2O2 concentration and the flow rate of the reactor were examined. 4.1 log reductions of bacteria with 52% and 39% of BOD and COD reductions in 45 min of treatment were observed. The catalyst was also found to be highly durable, with only a 12.5% of reduction in catalyst activity observed after 200 recycles. Therefore, this pilot-scale research indicates the ability of waste materials to be employed as a practical approach for water disinfection applications.

Keywords: Disinfection; Hybrid process; Photo-Fenton; Photocatalysis; Solar irradiation.

MeSH terms

  • Disinfection
  • Hydrogen Peroxide
  • Titanium
  • Wastewater*
  • Water
  • Water Purification*

Substances

  • Wastewater
  • titanium dioxide
  • Hydrogen Peroxide
  • Titanium
  • Water