The availability of potable drinking water is a tough challenge particularly in arid and semiarid regions as it is closely linked to human health. Fluoride and nitrate are widely reported concern in different districts of Rajasthan. Therefore, this study was engaged in the Churu District of Rajasthan to appraise the water quality especially in reference to fluoride and nitrate and health risk associated with its consumption. The overall potability of water was evaluated using water quality index and PCA indicated major sources responsible for water contamination. A total of 515 groundwater samples were collected from different locations of Churu District and16 water quality parameters were analyzed as per the standard protocol of APHA. The results showed that the values for all analyzed water quality parameters were greater than the prescribed limit of WHO and BIS. F- levels in 191 samples and nitrate levels in 147 samples were found to be over than BIS-acceptable limit. The results of the fluoride and nitrate risk assessment revealed that the Hazard Index value was greater than one of 393 groundwater samples for males, 403 groundwater samples for females, and 397 groundwater samples for children, indicating that drinking groundwater poses a significant health risk in the study area. Only 46.02 percent of groundwater samples may be utilized for drinking, according to the water quality index (WQI), while the remaining are unfit for drinking purpose without treatment. The huge number of variables impacting the overall quality and chemistry of groundwater were reduced using principal component analysis (PCA), which identified four key components that account for 69.11 percent of variance in the dataset. The PCA indicated that both geogenic and anthropogenic factors significantly influenced the water quality of the study region.
Keywords: Fluoride and nitrate; Groundwater; Health risk; PCA; WQI.
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