High-efficiency degradation catalytic performance of a novel Angelica sinensis polysaccharide-silver nanomaterial for dyes by ultrasonic cavitation

Hao Jiang; Haonan Lu; Yongshan Zhou; Yongfeng Liu; Changchun Hao

doi:10.1016/j.ultsonch.2023.106289

High-efficiency degradation catalytic performance of a novel Angelica sinensis polysaccharide-silver nanomaterial for dyes by ultrasonic cavitation

Ultrason Sonochem. 2023 Feb:93:106289. doi: 10.1016/j.ultsonch.2023.106289. Epub 2023 Jan 5.

Authors

Hao Jiang¹, Haonan Lu¹, Yongshan Zhou¹, Yongfeng Liu², Changchun Hao³

Affiliations

¹ Shaanxi Key Laboratory of Ultrasound, Shaanxi Normal University, Xi'an 710062, China; College of Food Engineering and Nutritional Science, Shaanxi Normal University, Xi'an 710062, China.
² Shaanxi Key Laboratory of Ultrasound, Shaanxi Normal University, Xi'an 710062, China; College of Food Engineering and Nutritional Science, Shaanxi Normal University, Xi'an 710062, China. Electronic address: biophymed@snnu.edu.cn.
³ Shaanxi Key Laboratory of Ultrasound, Shaanxi Normal University, Xi'an 710062, China; College of Food Engineering and Nutritional Science, Shaanxi Normal University, Xi'an 710062, China. Electronic address: haochangchun@snnu.edu.cn.

Abstract

Currently, the polluted wastewater discharged by industry accounts for the major part of polluted bodies of water. As one of the industrial wastewaters, dye wastewater is characterized by high toxicity, wide pollution, and difficulty in decolorization degradation. In this paper, a novel composite nanomaterial catalyst of silver was prepared by using Angelica sinensis polysaccharide (ASP) as a reducing and stabilizing agent. And the optimum reaction conditions explored are V_AgNO3 = 5 mL (300 mM) and v_ASP = 7% (w/v) for 6 h at 90 °C. In addition, the ASP-Ag nanocatalyst was characterized by several techniques. The results demonstrated that ASP-Ag nanoparticles were successfully synthesized. Degradation rate, which provides a numerical visualization of the percentage reduction in pollutant concentration. With the wrapping of ASP, the ultrasonic catalytic degradation rates of different organic dyes including rhodamine B (RB), methylene blue (MB), and methyl orange (MO) were from 88.2%, 88.7%, and 85.2% to 96.1%, 95.2% and 93.5% at room temperature, respectively. After the experiments, when c_dyes = 10 mg/L, the highest degradation rate can be observed under c_APS-AgNPs = 10 mg/L with the most powerful cavitation frequency f = 59 kHz. The effect of ultrasonic frequency on the acoustic pressure distribution in the reactor was investigated by using COMSOL Multiphysis^@ software to propose the mechanism of ultrasonic degradation and the mechanism was confirmed by OH radical trapping experiments. It indicates that OH produced by the ultrasonic cavitation effect plays a determinant role in the degradation. And then, the intermediate products of the dye degradation process were analyzed by gas chromatography and mass spectrometry (GC-MS), and the possible degradation processes of dyes were proposed. The resulting products of degradation are SO₄^2-, NH₄⁺, NO₃^-, N₂, CO₂ and H₂O. Finally, the recycling degradation experiments showed that catalyst maintains a high degradation rate within reusing 5 cycles. Thus, this catalyst is highly efficient and recyclable.

Keywords: Angelica sinensis polysaccharide; Organic dyes; Silver nanoparticles; Ultrasonic cavitation; Ultrasonic degradation.