Heterogeneous Fenton oxidation of 2,4-dichlorophenol catalyzed by PEGylated nanoscale zero-valent iron supported by biochar

Abstract

The excessive use of herbicides and fungicides containing 2,4-dichlorophenol (2,4-DCP) has led to serious environmental water pollution; 2,4-DCP is chemically stable and difficult to be degraded effectively by biological and physical methods. And the degradation of 2,4-DCP using advanced oxidation techniques has been a hot topic. Biochar, polyethylene glycol, ferrous sulfate, and sodium borohydride were used to synthesize the heterogeneous catalyst PEGylated nanoscale zero-valent iron supported by biochar (PEG-nZVI@BC). The catalyst was characterized using scanning electron microscope (SEM) and other means to determine its physicochemical properties. Catalytic performance and mechanism of this catalyst with hydrogen peroxide for the oxidation of 2,4-DCP were investigated. The results showed that PEG-nZVI@BC had good dispersibility, stability, and inoxidizability; the degradation efficiency of 50 mg/L 2,4-DCP by PEG-nZVI@BC/H₂O₂ system 92.94%, 1.68 times higher than that of nZVI/H₂O₂ system; there are both free radical and non-free radical pathways in PEG-nZVI@BC/H₂O₂ system; the degradation process of 2,4-DCP includes hydroxylation, dechlorination, and ring-opening. Overall, PEG-nZVI@BC is a promising heterogeneous catalyst for the degradation of 2,4-DCP.

Keywords: 2,4-dichlorophenol; Biochar; Fenton oxidation; Nanoscale zero-valent iron; Polyethylene glycol.