Exploring highly efficient microwave absorption (MA) materials with a facile preparation method is of great significance for tackling electromagnetic pollution and remains a challenge. Herein, ternary MoO2/Mo2C/Mo2N composites with porous structures are fabricated by a simple precursor pyrolysis process. The unique structure and multiple components, which could generate sufficient heterogeneous interfaces, are conducive to improve impedance matching, trigger polarization loss, and strengthen conduction loss. Profiting from the synergistic effect of multiple dissipation mechanisms, the composites exhibit exceedingly good MA performance. The minimum reflection loss value reaches -38.0 dB at 10.4 GHz when the thickness is 2.0 mm, and the maximum effective absorbing bandwidth is 4.11 GHz ranged from 12.41 to 16.52 GHz when the thickness is 1.5 mm. These strategies pave opportunities for rational design of Mo-related composites for high-efficiency electromagnetic-wave absorption performance.