Piezoelectric nanogenerators (PENGs) provide a viable solution to convert the mechanical energy generated by body movement to electricity. One-dimensional yarns offer a platform for flexible wearable textile PENGs, which can conform to body for comfort and efficient energy harvesting. In this context, we report a flexible piezoelectric yarn, assembled by one-step cocentric deposition of cesium lead halide perovskite decorated polyvinylidene fluoride (PVDF) nanofibers, on a stainless-steel yarn. Perovskite crystals were formed in situ during electrospinning. Our work demonstrates a nanofiber morphology in which perovskite crystals spread over the nanofiber, leading to a rough surface, and complementing piezoelectric nanocomposite formation with PVDF for superior stress excitation. We investigated how the halide anions of perovskite affect the piezoelectric performance of PENG yarns by comparing CsPbBr3 and CsPbI2Br. Effects of the perovskite concentration, annealing temperature, and deposition time on the piezoelectric properties of PENG yarns were investigated. Devices assembled with a single yarn of CsPbI2Br decorated PVDF nanofibers yield the optimal performance with an output voltage of 8.3 V and current of 1.91 μA in response to pressing from an actuator and used to charge capacitors for powering electronics. After aging in the ambient environment for 3 months, the device maintained its performance during 19,200 cycles of mechanical stresses. The excellent and stable electrical performance can be ascribed to the optimized crystallization of CsPbI2Br crystals, their complementing performance with PVDF, and formation of nanofibers with uniformity and strength. The flexibility of piezoelectric yarns enables them to be bent, twisted, braided, and woven for different textile integrations while harvesting energy from body movements, demonstrating the potential for wearable mechanical energy harvesting.
Keywords: composite nanofibers; electrospinning; perovskite; piezoelectric yarn; polyvinylidene fluoride.