This research aims to enhance the mechanical characteristics of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) by using epoxidized natural rubber (ENR-25 and ENR-50) as a toughening agent and polybutadiene (PB) grafted with maleic anhydride (MA) (3 MA groups/chain) as a compatibilizer. The PHBV/ENR blends were mixed in 100/0, 90/10, 80/20, and 70/30 with PB-g-MA at 0, 5, and 10% (wt./wt.), using an internal mixer set to 175 °C with a rotor speed of 50 rpm. The findings indicated that at 70/30 PHBV/ENR composition, the impact strength of the blends with 25 and 50 epoxide contents were the greatest at 6.92 ± 0.35 J m-1 and 7.33 ± 1.19 J m-1, respectively, which are about two times greater than that of neat PHBV. Furthermore, the biodegradability of the PHBV/ENR blends was more substantial than that of neat PHBV, showing a mass reduction of approximately 40% and 45% for PHBV/ENR-25 and PHBV/ENR-50, respectively. In comparison, while the mass loss of PHBV was approximately 37% after three months of soil burial. The results indicate that ENR improves the toughness of the blends while simultaneously increasing PHBV degradation, which could pave the way for broadening PHBV for sustainability purposes.
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