Fabrication of chitosan-MnO2‑iridium/nanoceria supported nanoparticles: Catalytic and anti-radical activities

Abstract

Chitosan capped MnO₂‑iridium nanoparticles supported on nanoceria (Ch-MnO₂-Ir/CeO₂) were fabricated by using combination of colloidal solution and metal displacement galvanic methods. The oxidative degradation of acid orange 7 in aqueous solution by activated persulfate with the as-prepared nanoparticles was studied. The resulting Ch-MnO₂-Ir/CeO₂ with S₂O₈^2-, 80 % degraded 70.06 mg/L of acid orange 7 within 100 min, while at the same time, Ch-Ir, Ch-MnO₂, and Ch-Ir-MnO₂ remained inactive. CeO₂ increased the surface of the catalyst, and also improved the reactive oxygen species site of Ch-Ir-MnO₂ through the activation of S₂O₈^2- with CeO₂. The reversible redox cycle reaction, Ce (III) ↔ Ce (IV) and strong synergistic effect of MnO₂-Ir are responsible for the remarkable catalytic performance of Ch-MnO₂-Ir/CeO₂/S₂O₈^2- system. The degradation of acid orange 7 could be significantly retarded with inorganic (NO₃^- < Cl^- < SO₄^2- < H₂PO₄^- < HCO₃^-) and organic scavengers (ethanol < tertiary butanol < benzoquinone < phenol). Ch-MnO₂-Ir/CeO₂ exhibited excellent stability and reusability. Anti-radical activity of chitosan and Ch-MnO₂-Ir/CeO₂ was evaluated with 2,2-diphenyl-1-picrylhydrazyl (DPPH) free radical. The free radical properties increase with concentration of chitosan and Ch-MnO₂-Ir/CeO₂.

Keywords: CeO(2) supported Ch-MnO(2)-Ir; Persulfate activation; Scavenging effect.